Spatial Trends of Anionic, Zwitterionic, and Cationic PFASs at an AFFF-Impacted Site

TRRP Training: 2022 Program

presented by: GSI Environmetal Inc.

Texas Risk Reduction Program regulations (TRRP; 30 TAC 350) establish consistent risk-based protocols for assessment and response to soil, groundwater, or surface water impacts associated with environmental releases of regulated wastes or substances.

Presented by GSI Environmental Inc., this popular and informative training series is a must for professionals who need a working understanding of TRRP and those needing to stay up-to-date with the latest TCEQ TRRP guidance and policies.

TRRP Training Course (2 Days): Provides an overview of the TRRP framework and step-by-step training on property assessment and response action procedures established under the TRRP rule

Attendees will become acquainted with rules, key guidance and policies covering affected property assessments, protective concentration levels, and response actions. The course material presents strategies for efficient project management in compliance with TRRP and explains the various report forms adopted by TCEQ.

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Dates and Location

Dates

June 14th and 15th, 2022

Location

Crowne Plaza River Oaks 2712 SW Freeway Houston, Texas 77098 713.523.8448 http://www.crowneplaza.com/

Price and Registration

Early-Bird Price

(Paid by May 1, 2022)
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(Paid after May 1, 2022)
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Authors: Anastasia Nickerson, Alix E. Rodowa, David T. Adamson, Jennifer A. Field, Poonam R. Kulkarni, John J. Kornuc, Christopher P. Higgins

Published: December 2020 in Environmental Science and Technology.

Abstract
Soil and groundwater from an aqueous film-forming foam (AFFF)-impacted site were sampled at high resolution (n = 105 for soil, n = 58 for groundwater) and analyzed for an extensive list of anionic, zwitterionic, and cationic poly- and perfluoroalkyl substances (PFASs). Spatial trends for perfluoroalkyl acids and many precursors enabled a better understanding of PFAS composition, transport, and transformation. All PFASs without analytical standards were semi-quantified. Summed PFAS and individual PFAS concentrations were often higher at depth than near the surface in soil and groundwater. Zwitterionic and cationic compounds composed a majority of the total PFAS mass (up to 97%) in firefighter training area (FTA) soil. Composition of PFAS class, chain length, and structural isomers changed with depth and distance from the FTA, suggesting in situ transformation and differential transport. The percentage of branched perfluorooctane sulfonate increased with depth, consistent with differential isomeric transport. However, linear perfluorooctanoic acid (PFOA) was enriched, suggesting fluorotelomer precursor transformation to linear PFOA. Perfluorohexane sulfonamide, a potential transformation product of sulfonamide-based PFASs, was present at high concentrations (maximum 448 ng/g in soil, 3.4 mg/L in groundwater). Precursor compounds may create long-term sources of perfluoroalkyl acids, although many pathways remain unknown; precursor analysis is critical for PFAS fate and transport understanding.